鄱阳湖流域多尺度C、N输送通量及其水质参数变化特征

本文选取鄱阳湖流域内从初级支流到最大干流再到湖区(香溪→架竹河→赣江→鄱阳湖)这一联通水系线路为研究对象,通过对丰水期和枯水期内各级河流对应流域及鄱阳湖湖区内水体中的各形态C、N浓度进行监测,计算各级河流间C、N元素运移通量,探讨鄱阳湖流域水体C、N迁移过程机制和水质参数变化特征,为鄱阳湖流域生态系统的综合健康管理提供科学依据.结果表明:(1)鄱阳湖通江流域的C、N浓度呈明显季节变化,其中TIC、TOC、TC浓度丰水期较高,而NO_3~--N和DTN浓度枯水期较高.丰水期TC增加的主要原因是TIC增加,丰水期TN主要以非溶解态存在,而枯水期TN主要以DTN中的NO_3~--N形式存在.(2)鄱阳湖通江流域的C、N输出通量呈明显季节变化,其中香溪各形态C丰水期通量较枯水期小,架竹河、赣江各形态C丰水期通量较枯水期大,香溪、架竹河、赣江流域各形态N在丰水期通量大多较枯水期小,各形态C、N通量与径流量在99%的置信水平上呈极显著正相关关系.(3)鄱阳湖流域水体参数丰水期COND、TDS、pH小于枯水期,丰水期ORP大于枯水期.     

输水水质保障下南四湖流域产业结构优化调整研究

通过对南四湖流域产业结构现状、水污染现状以及两者动态演化趋势的解析,结合对流域经济与环保政策导向的梳理,综合权衡三次产业发展对流域经济支撑度、水污染影响潜在威胁与现实效应,汇总形成了南四湖流域三次产业结构优化调整分析矩阵。在此基础上,探讨了不同产业结构优化调整的方案模式,提出南四湖流域三次产业中不同行业的结构优化方案。     

输水水质保障约束下的南四湖流域产业生态化发展研究

在生态文明建设理念的指导下,从南四湖流域的自身特点与现状出发,在总结和借鉴国内外产业生态发展主要经验的基础上,结合南四湖流域自身特点,从管理机制、财政政策、价格税收、技术创新、投资取向、政绩考核等多角度出发,构建了南四湖流域的产业生态政策体系,并从实施目标责任考核、建立流域产业布局规划的协调制度、完善产业结构调整优化的法律法规制度、增强生态产业的科技创新能力、建立流域的政府信息共享与公开机制、建立健全流域水环境执法机构六个方面提出了相应的生态保障措施。     

一个新的分布式水文模型在鄱阳湖赣江流域的验证

考虑同类模型在模拟大尺度流域时存在的一些弱点，开发了基于单元网格，并且结构较为简单、参数数量较少的分布式水文模型WATLAC。为了验证该模型在大尺度流域长时间序列的模拟效果，选取鄱阳湖流域的最大子流域——赣江流域（817万km2）为验证区域。流域的空间非均匀性由单元网格离散并模拟。根据下垫面数据精度，选取4 km×4 km的离散网格尺寸，并应用ArcGIS等软件建立流域网格信息，生成模型输入数据。采用1960~1989年外洲站和峡江站的实测资料对模型进行了验证。率定期（1960~1969年）两水文站日、月和年径流确定性系数在081~093，Ens系数在079~099，年径流统计量相对误差均低于8%；校核期（1970~1989年）两水文站日、月和年径流确定性系数在076~092，Ens系数在075~091，年径流统计量相对误差均低于2%。结果显示，模拟的径流量与实测值吻合良好，模型在赣江流域得到了很好的验证。模型对赣江流域具有较强的适用性，在流域水资源管理中具有较好的应用前景。     

Distribution of polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans, dioxin-like polychlorinated biphenyl and polycyclic aromatic hydrocarbons in the sediment of Temsah lake, Suez Canal, Egypt

Lake Temsah is one of the main wetlands in the Suez Canal region, and the main source for fish for the area. The lake is the end-point of several wastewater effluents. In the present study, residues of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs), dioxin-like polychlorinated biphenyl (PCB) and polycyclic aromatic hydrocarbons (PAH) were monitored in the sediment of the lake. Samples were collected from six different sampling stations around the lake using a box-corer sampler, then kept frozen. Samples were extracted and cleaned up before residue determination was conducted using an HRGC/HRMS. An HP 6890 plus gas chromatograph was coupled to a Micromass Autospec Ultima mass spectrometer operating in EI mode at 35 eV and with a resolution of 10.000 (5% valley). PCDDs and PCDFs were detected in all sediment samples collected from various sampling stations. Results showed some progressive increase in PCDDs concentrations relevant to increase in chlorination. In the PCDD group of congeners, 1, 2, 3, 4, 6, 7, 8, 9 octa-CDD had the highest detected concentrations in all samples, while 2, 3, 7, 8 tetra-CDD showed the lowest concentrations. The World Health Organization toxicity equivalents ranged from 0.387 to 11.20 ng kg^-1 d.w. For PCDD homologues, hexa-CDD was the most dominant homologue in all sediment samples analysed. Regarding dioxin-like PCBs, results showed that IUPAC No. 118 congener, 2, 3, 4, 4, 5, pentachlorobiphenyl was the most concentrated of all detected congeners, with concentrations ranging between 0.039 and 43.201 µg kg^-1. For polycyclic aromatic hydrocarbons, benzo(b+k+j)fluoranthene had the highest concentrations in almost all sampling stations. However, fluorene was the smallest detected concentration in almost all stations. This result would indicate that PAH contamination of the lake seems to be coming from one main source in all sampling stations. The present work is the first record of PCCDs, PCCFs, and dioxin-like PCBs in the Temsah lake. The concentrations of the contaminants monitored in this study, especially those of PAHs, are rather alarming. Efforts should be made to stop point sources that contaminate the lake.     

太湖生态修复治理工程

太湖是我国第三大淡水湖泊 ,也是流域的重要水体。近年来 ,随着人口的增长 ,经济高速发展 ,人为社会经济活动影响 ,水资源系统受到很大冲击 ,水质变劣 ,湖体营养过程加剧 ,生态环境受到明显损害 ,制约了流域社会经济的可持续发展。要实现流域水资源的可持续利用 ,必须加快水污染综合治理。除陆域实施严格的达标治理、河网水质调控 ,农业面源及生活污水治理外 ,太湖湖体生态修复和富营养化治理已为当务之急。目前应尽早实施 :①太湖重污染区底泥的生态疏浚 ,减少底泥释放二次污染。②利用浮床陆生植物治理太湖典型富营养化水域 ,利用生物吸收、降解 ,继而富集营养盐 ,净化水质。③建立环湖湿地保护带。④恢复和重建湖滨带水生植被 ,实现长效生态管理和调控。⑤生态渔业工程 ,有效控制过度养殖 ,恢复湖泊生态良性循环。⑥藻类采集和资源化再利用。⑦强化流域     

长湖水环境质量与水生生物状况

对长湖水环境质量和水生生物状况进行了评价。结果表明：长湖水质污染属有机污染型，总体评价属V类或劣V类水质，长湖属极富营养型湖泊。藻类群落结构随季节变化，其中，夏季长湖蓝藻为优势类群；磷是长湖藻类生长的限制因子；夏秋季浮游动物数量明显高于冬春季；菹草（Potamogeton crispus）、微齿眼子菜（Potamogeton maackianus）为沉水植物主要群落类型，水生维管束植物分布占全湖面积的80％～90％，春季生物量较高；藻类与沉水植物的生长处于相对平衡的状态。     

洞庭湖区不同利用方式下农田土壤有机碳含量特征

土地利用方式是影响土壤有机碳含量和动态的重要因子之一。其利用方式的改变必将引起土壤有机碳含量发生相应的变化。在洞庭湖腹地选取典型样区，通过调查走访和密集取样，分析了不同土地利用方式（旱地、水旱轮作地、一季稻水田和双季稻水田）下623个农田耕层土样有机碳含量。结果表明，研究区内土壤有机碳含量高低顺序为双季稻水田（28.12 g/kg） > 一季稻水田（27.03 g/kg） > 水旱轮作地（24.79 g/kg） > 旱地（17.96 g/kg），其差异均达到极显著水平（P < 0.01）。土地生产力、秸秆还田量和土壤水文状态是导致不同利用方式下耕层土壤有机碳含量差异的主要原因。进一步分析表明：加强作物秸秆还田（土）、提高土地复种指数、增加地表覆盖是维持和提高洞庭湖区耕作土壤有机碳含量的可行措施，尤其是旱作土壤。     

西洞庭湖鱼类物种多样性及其时空变化

洞庭湖是长江中游现存仅有的两大通江湖泊之一，研究其鱼类资源对了解湖泊通江的生态作用有着重要意义。为此，在2002年9月~2004年6月每月定期定点在西洞庭湖区开展鱼类调查，结果如下：① 实地调查到鱼类111种，隶属9目20科，包括中华鲟、胭脂鱼等珍稀物种；②鱼类物种数年动态波动较大,最高月份达69种，最低为26种，月均50±13种；③物种多样性指数年动态与物种数年动态大体一致，最高达3.34，最低为1.89，月均2.84±0.38；④空间分布上，位于入湖口的调查点物种数和多样性指数高于内湖，且差异有显著性(p<0.05)；⑤在数量上，湖泊定居型鱼类占50%以上，其中，鲫数量最多，占16%左右。可见：西洞庭湖作为通江湖泊在鱼类多样性的保护上起到避难所和交流场所的作用；目前，西洞庭湖鱼类在生态组成上，湖泊定居型鱼类比重有逐渐增加的趋势。     

The Status of Pesticide Residues in the Drinking Water Sources in Meiliangwan Bay, Taihu Lake of China

The study was carried out to assess the levels of pesticide residues in the water of Meiliangwan Bay, Taihu Lake of China. The most commonly employed organochlorine pesticides (OCPs), organophosphorus pesticides (OPPs) and herbicide atrazine were analyzed. The water samples were collected seasonally from Meiliangwan Bay within a period of one year. The pesticides were analyzed by gas chromatography (GC) with μECD or NPD after solid-phase extraction (SPE), which was confirmed by GC with an ion trap mass spectrometry (MS). The mean concentrations were 1.98 ng/l for lindane, 0.378 ng/l for heptachlor epoxide, 0.367 ng/l for p,p′-DDE, 0.496 ng/l for p,p′-DDD, 1.06 ng/l for p,p′-DDT and 51.6 ng/l for dichlorvos, 39.0 ng/l for demeton, 346 ng/l for dimethoate, 4.12 ng/l for methyl parathion, 11.6 ng/l for malathion, 2.17 ng/l for parathion and 217 ng/l for atrazine. Generally, low concentrations of OCP were found, whereas the concentrations of the OPPs and atrazine in the water of Taihu Lake were relatively high. Heptachlor epoxide and lindane were the two most commonly encountered OCPs while dichlorvos, demeton and dimethoate were found to have much higher concentrations and occurrences than other OPPs.